Zeolitic catalysts with chemisorbed methyl groups
نویسندگان
چکیده
منابع مشابه
Quasi-free methyl rotation in zeolitic imidazolate framework-8.
Using neutron inelastic scattering and diffraction, we have studied the quantum methyl rotation in zeolitic imidazolate framework-8 (ZIF-8: Zn(MeIM)(2), MeIM = 2-methylimidazolate). The rotational potential for the CH(3) groups in ZIF-8 is shown to be primarily 3-fold in character. The ground-state tunneling transitions at 1.4 K of 334 +/- 1 mueV for CH(3) groups in hydrogenated ZIF-8 (H-ZIF-8)...
متن کاملMethyl viologen-templated zinc gallophosphate zeolitic material with dual photo-/thermochromism and tuneable photovoltaic activity.
A novel zinc gallophosphate zeolitic material |(C12H14N2)4F1.33|[Ga13.33Zn6.67(PO4)20] (denoted as JU101) has been prepared by using in situ generated methyl viologen (MV) as the template. The framework of JU101 features two building units including an unprecedented fused d6r and a novel [412·64·82·102] cavity. The connection of these two building units forms a 3D intersecting pore system conta...
متن کاملEnhancement of Brønsted acidity in zeolitic catalysts due to an intermolecular solvent effect in confined micropores.
Solid-state NMR and DFT calculation studies certified the presence of an intermolecular solvent effect for molecules confined in microporous zeolite, leading to a notable increase in Brønsted acidity of the solid acid catalyst.
متن کاملMethyl groups or additional aromatic groups donate tumour promoting activity.
There are many examples in chemical carcinogenesis in which the introduction of methyl groups or aromatic rings increased the potency of polycyclic hydrocarbons and aromatic amines. Examination of the data in the light of the multistage process of carcinogenesis indicates that these groups convert initiators into complete carcinogens. As complete carcinogens have both initiating and promoting a...
متن کاملMethyl tunnelling of adsorbed methoxy on alumina catalysts.
The aim of this paper is to investigate whether the methyl group of the adsorbed methoxy intermediate on industrial grade alumina catalysts undergoes rotational tunnelling on the wavenumber energy scale. The data show that this is clearly the case for a fraction of the methyl groups and potentially allows the subtle intermolecular interactions between adsorbed species and catalyst to be probed ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2000
ISSN: 0108-7673
DOI: 10.1107/s0108767300028129